Cluster complexes [Mo3O2S2(Acac)3(Amine)3]PF6

Autor:	J. A. Laricheva, Eugenia V. Peresypkina, Maxim N. Sokolov, Pavel A. Abramov
Rok vydání:	2014
Předmět:	Pyrazine General Chemical Engineering Inorganic chemistry chemistry.chemical_element Infrared spectroscopy General Chemistry Crystal structure Mass spectrometry Medicinal chemistry chemistry.chemical_compound chemistry Molybdenum Morpholine Cluster (physics) Amine gas treating
Zdroj:	Russian Journal of Coordination Chemistry. 40:171-178
ISSN:	1608-3318 1070-3284
Popis:	New mixed-ligand cluster complexes [Mo3O2S2(Acac)3(Amine)3]PF6 (Amine = morpholine (Mor), 4-cyanopyridine (PyCN), pyrazine (Pz)) have been synthesized. The compounds were characterized by IR spectroscopy and mass spectrometry (ESI-MS). The crystal structure of the Mor complex, which was isolated as [Mo3(μ3-S)(μ2-O)2(μ2-S)(Acac)3(Mor)3]PF6 · 0.5Mor · 0.3(CH3)2CO was determined. The stability of the complexes in methanolic solutions decreases in a row: Mor > PyCN > Pz.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eddd5f885042ee9be2c4dbf26f506020 https://doi.org/10.1134/s1070328414030014 Zobrazit plný text záznamu Full text from SpringerLink