Unusual Electrochemical Properties of the Inclusion Complexes of Ferrocenium and Cobaltocenium with Cucurbit[7]uril

Autor:	Winston Ong, Angel E. Kaifer
Rok vydání:	2003
Předmět:	Inorganic Chemistry Crystallography Chemistry Organic Chemistry Physical and Theoretical Chemistry Absorption (chemistry) Electrochemistry Equilibrium constant
Zdroj:	Organometallics. 22:4181-4183
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om030305x
Popis:	Ferrocenium and cobaltocenium form highly stable 1:1 inclusion complexes with the host cucurbit[7]uril. From electronic absorption spectroscopic data the association equilibrium constants for both complexes were found to be larger than 106 L/mol. The electrochemical reduction of either guest leads to a modest loss in binding affinity.
Databáze:	OpenAIRE
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