Determination of the rate constants of addition of.P(O)(OPri)2 radicals to fullerenes C60 and C70

Autor: Vasily V. Bashilov, R. G. Gasanov, O. G. Kalina, Boris Tumanskii
Rok vydání: 2000
Předmět:
Zdroj: Russian Chemical Bulletin. 49:1642-1644
ISSN: 1573-9171
1066-5285
DOI: 10.1007/bf02495175
Popis: The rate constants of the addition of phosphoryl radicals to fullerenes C60 and C70 were determined by the method of competitive reactions. The phosphoryl radicals were shown to be 1.5–3 orders of magnitude more reactive than the carbon-centered radicals.
Databáze: OpenAIRE