Crystal structure of a giant supramolecule encapsulating o-carborane

Autor:	Eugenia V. Peresypkina, Michael Bodensteiner, Manfred Scheer, Alexander V. Virovets, Claudia Heindl, Andrea Schindler
Rok vydání:	2014
Předmět:	Inorganic Chemistry Crystallography Materials science Carborane General Materials Science Crystal structure Condensed Matter Physics
Zdroj:	Zeitschrift für Kristallographie - Crystalline Materials. 229:735-740
ISSN:	2196-7105 2194-4946
Popis:	A giant quasi-spherical supramolecule [{Cp*Fe(η5-P5)}12(CuBr)18.8] encapsulating o-carborane was prepared by the reaction between CuBr and [Cp*Fe(η5-P5)] (Cp* = pentamethylcyclopentadienyl) and structurally characterized. The crystal structure can be treated as solid solution of various [(Cp*Fe(η5-P5))12(CuBr)n] supramolecules with n = 18–20. Two crystals obtained from different syntheses differ in the location of vacant CuBr positions and solvent molecules. Surprisingly, the supramolecules are packed following the low-density reo (ReO3) packing.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::edb841516fa6d932d345b4410ea5d126 https://doi.org/10.1515/zkri-2014-1755 Zobrazit plný text záznamu