Crystal structure of a giant supramolecule encapsulating o-carborane
Autor: | Eugenia V. Peresypkina, Michael Bodensteiner, Manfred Scheer, Alexander V. Virovets, Claudia Heindl, Andrea Schindler |
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Rok vydání: | 2014 |
Předmět: | |
Zdroj: | Zeitschrift für Kristallographie - Crystalline Materials. 229:735-740 |
ISSN: | 2196-7105 2194-4946 |
Popis: | A giant quasi-spherical supramolecule [{Cp*Fe(η5-P5)}12(CuBr)18.8] encapsulating o-carborane was prepared by the reaction between CuBr and [Cp*Fe(η5-P5)] (Cp* = pentamethylcyclopentadienyl) and structurally characterized. The crystal structure can be treated as solid solution of various [(Cp*Fe(η5-P5))12(CuBr)n] supramolecules with n = 18–20. Two crystals obtained from different syntheses differ in the location of vacant CuBr positions and solvent molecules. Surprisingly, the supramolecules are packed following the low-density reo (ReO3) packing. |
Databáze: | OpenAIRE |
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