Coordination Chemistry of Bidentate Bis(NHC) Ligands with Two Different NHC Donors

Autor:	F. Ekkehardt Hahn, Tania Pape, Sabrina Schick
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Denticity Tetrafluoroborate Chemistry Stereochemistry Ligand Organic Chemistry Triazole Medicinal chemistry Coordination complex Inorganic Chemistry Azine chemistry.chemical_compound Moiety Chelation Physical and Theoretical Chemistry
Zdroj:	Organometallics. 33:4035-4041
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om500554t
Popis:	Reaction of N-aminobenzimidazole 1 or N-aminoimidazole 2 with N,N-bis(dimethyleneamin)azine 3 yielded the biazoles 4-(benzimidazol-1-yl)-4H-[1,2,4]triazole 4 and 4-(imidazol-1-yl)-4H-[1,2,4]triazole 5. Double N,N-alkylation yielded the new bis(NHC) precursors 1-methyl-4-(3-methylbenzimidazol-1-yl)-4H-[1,2,4]triazolium tetraffluoroborate [6a](BF4)2, 1-ethyl-4-(3-ethylbenzimidazol-1-yl)-4H-[1,2,4]triazolium tetrafluoroborate [6b](BF4)2, and 1-methyl-4-(3-methylimidazol-1-yl)-4H-[1,2,4]triazolium tetrafluoroborate [7](BF4)2, each featuring a triazolium moiety in addition to a benzimidazolium or imidazolium group linked together by a N–N bond. The diazolium salts react with Pd(OAc)2 to give the bis(NHC) complexes [8a](BF4)2, [8b](BF4)2, and [9](BF4)2, each bearing an unsymmetrical triazolylidene/benzimidazolylidene or triazolylidene/imidazolylidene dicarbene ligand coordinated in a chelating fashion to the metal center.
Databáze:	OpenAIRE
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