Hydrothermal synthesis and single-crystal structural characterization of VO(VO3)6(VO(C10H8N2)2)2
| Autor: | Guohe Huan, Joseph S. Merola, Allan J. Jacobson, Jack W. Johnson |
|---|---|
| Rok vydání: | 1991 |
| Předmět: |
chemistry.chemical_classification
Stereochemistry Space group Crystal structure Condensed Matter Physics Electronic Optical and Magnetic Materials Inorganic Chemistry Crystallography chemistry Octahedron X-ray crystallography Materials Chemistry Ceramics and Composites Hydrothermal synthesis Physical and Theoretical Chemistry Single crystal Inorganic compound Monoclinic crystal system |
| Zdroj: | Journal of Solid State Chemistry. 91:385-389 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/0022-4596(91)90094-x |
| Popis: | VO(VO3)6(VO(C10H8N2)2)2 has been synthesized by the hydrothermal reaction of V2O3 with 2,2′-bipyridine. The compound is monoclinic, space group P2 1 n (No. 14), a = 7.579 (2) A, b = 26.713 (8) A, c = 12.776 (3) A, β = 94.97 (2)°, Z = 2. Its structure consists of (VO3)n chains of corner-sharing pentavalent vanadium tetrahedra joined by V4+ square pyramids, with octahedral VO(C10H8N2)2 groups arrayed on the periphery of the chains. The V4+ sites are isolated magnetically, with the compound exhibiting Curie-Weiss behavior in the temperature range 10–300 K. The calculated μeff is 1.68 μ B V 4+ , close to the spin-only value. |
| Databáze: | OpenAIRE |
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