Synthesis and characterization of phenolic and amino resins based on α, β-unsaturated aldehydes

Autor: Anton Šebenik, Uči Osredkar, Majda Žigon
Rok vydání: 1992
Předmět:
Zdroj: Journal of Applied Polymer Science. 45:597-606
ISSN: 1097-4628
0021-8995
DOI: 10.1002/app.1992.070450406
Popis: henolic and amino resins on the basis of α,β-unsaturated aldehydes were synthesized in bulk or solution. Catalysts were HCl, H 3 PO 4 , or formic acid, and in some cases NaOH. The course of the reactions is influenced by experimental conditions: the type of monomers, their molar ratio, the type and quantity of the catalyst, the reaction time and temperature, and the reaction medium. The overall rate constants for the beginning of the reactions were between 10 -3 L/mol s for the high reactive mixtures and 10 -7 L/mol s for the less reactive mixtures.
Databáze: OpenAIRE