ChemInform Abstract: Successful Application of Marcus Theory to Catalysis by Labile Metal Ions

Autor:	Daniel L. Leussing
Rok vydání:	2010
Předmět:	Reaction mechanism Reaction rate constant Computational chemistry Chemistry Decarboxylation Metal ions in aqueous solution Inorganic chemistry Condensation General Medicine Keto–enol tautomerism Catalysis Marcus theory
Zdroj:	ChemInform. 30
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199926317
Popis:	The successful applications of Marcus theory to catalysis by labile metal ions in the base-catalyzed enolization and decarboxylation of oxalacetate and in the ketonization and condensation of enolpyruvate are described. Illustrations are presented describing the prediction of rate constants and the use of the theory in original and expanded versions to gain insight into possible features of a reaction mechanism.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ed90fb477f415052b1c29c28547fe196 https://doi.org/10.1002/chin.199926317 Zobrazit plný text záznamu Plný text