Extended structures based on hydrogen bonding and π–π interactions: synthesis and characterization of two zinc complexes: [Zn(dap)Cl2] and [Zn(dap)2Cl2]

Autor:	Rosario A. Vilaplana, Allison M. Mills, Anthony L. Spek, Huub Kooijman, Jan Reedijk, Carmen de Cires-Mejias, Francisco González-Vílchez, Stefania Tanase
Rok vydání:	2004
Předmět:	Inorganic Chemistry chemistry.chemical_compound Crystallography Denticity chemistry Hydrogen bond Pyridine Atom Materials Chemistry chemistry.chemical_element Zinc Physical and Theoretical Chemistry
Zdroj:	Inorganica Chimica Acta. 357:1494-1498
ISSN:	0020-1693
Popis:	Two new Zn(II) complexes, [Zn(dap)Cl 2 ] ( 1 ) and [Zn(dap) 2 Cl 2 ] ( 2 ) (dap stands for 2,3-diaminopyridine), were prepared and spectroscopically and crystallographically characterized. In both compounds, the zinc(II) atom has a pseudo-tetrahedral ZnN 2 Cl 2 coordination environment. Compound 1 adopts a three-dimensional structure built up from [Zn(dap)Cl 2 ] n zig-zag chains, which are linked by N–H⋯Cl hydrogen bonds. In compound 2 the dap is monodentate coordinating via the pyridine nitrogen; the mononuclear tetrahedral [Zn(dap) 2 Cl 2 ] units are linked into two-dimensional sheets through extensive N–H⋯Cl hydrogen bonding. Inter-sheet π–π interactions connect them into a three-dimensional network.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ed8bf71fb84acba7b66b48a5391eb72b https://doi.org/10.1016/j.ica.2003.11.035 Zobrazit plný text záznamu Full Text from ScienceDirect