Preparation and pyrolysis of tetramethyltetrazene–beryllium dialkyl complexes
Autor: | Neil R. Fetter |
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Rok vydání: | 1966 |
Předmět: | |
Zdroj: | J. Chem. Soc. A. :711-713 |
ISSN: | 0022-4944 |
DOI: | 10.1039/j19660000711 |
Popis: | The reactions of Me2NNNNMe2 with Et2Be,Pri2Be, and But2Be yielded 1:1 dative-bonded complexes and complexes with two beryllium alkyls per tetramethyltetrazene, the latter being more stable.Pyrolysis of the 2:1 compounds near 200°C has resulted in the formation of low molecular weight polymers containing BeH and RBe, perhaps serving as bridging groups, and Me2NNNNMe2 apparently serving as a linking agent for the beryllium atoms. |
Databáze: | OpenAIRE |
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