Jahn–Teller effect and the formation of anticorrosive protective layers of nitrilo-tris-methylene-phosphonates on surfaces of steel
| Autor: | V. A. Aleksandrov, I. N. Shabanova, I. V. Fedotova, A. L. Ul’yanov, F. F. Chausov, R. M. Zakirova, M. A. Shumilova, E. A. Naimushina, Nikolay V. Somov, V. G. Petrov |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
inorganic chemicals
Tris Materials science Jahn–Teller effect Inorganic chemistry General Physics and Astronomy chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Corrosion chemistry.chemical_compound Chromium chemistry Methylene 0210 nano-technology |
| Zdroj: | Bulletin of the Russian Academy of Sciences: Physics. 80:1310-1313 |
| ISSN: | 1934-9432 1062-8738 |
| DOI: | 10.3103/s1062873816110174 |
| Popis: | Nitrilo-tris-methylene-phosphonato-three-aqua-complexes of chromium(II) and iron(II), the main components of protective layers for inhibiting steel corrosion with nitrilo-tris-methylene-phosphonates, are isolated and studied. Their ability to form protective layers is explained by their insolubility and resistance to water and air. These properties of Cr and Fe complexes are explained by Jahn–Teller distortion of the coordination environment of Cr and Fe atoms. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink