[Fe(qdt)2]−salts; an undimerised FeIIIbisdithiolene complex stabilised by cation interactions

Autor:	M.J. Figueira, I.C. Santos, José A. Ayllón, R.T. Henriques, Sandra Rabaça, Dulce Simão, Manuel Almeida
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Crystallography chemistry Salt (chemistry) General Materials Science General Chemistry Condensed Matter Physics Square (algebra)
Zdroj:	CrystEngComm. 8:658-661
ISSN:	1466-8033
DOI:	10.1039/b602268e
Popis:	(n-Bu)4N[Fe(qdt)2] provides the first example of an undimerised FeIII bisdithiolene complex with well isolated square planar coordinated [Fe(qdt)2]− units, due to short apical Fe⋯H, Fe⋯C and S⋯H contacts with the cations, while the tetraphenylarsonium salt of this complex presents the usual dimerisation as [Fe(qdt)2]22−, with square-based pyramidal coordination of Fe.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ed638bdc777a4cb7c879db2ca8ed31d3 https://doi.org/10.1039/b602268e Zobrazit plný text záznamu