Electric fields drive bond homolysis

Autor: Boyuan Zhang, Cedric Schaack, Claudia R. Prindle, Ethan A. Vo, Miriam Aziz, Michael L. Steigerwald, Timothy C. Berkelbach, Colin Nuckolls, Latha Venkataraman
Rok vydání: 2023
Předmět:
Zdroj: Chemical Science. 14:1769-1774
ISSN: 2041-6539
2041-6520
DOI: 10.1039/d2sc06411a
Popis: We demonstrate that electric fields can homolytically cleave a peroxide bond in different solvents with a rate that is proportional to the solvent dielectric constant.
Databáze: OpenAIRE