Molecular and Crystal Structure of Binary Gold Fluorides
| Autor: | L. A. Palkina, Sh. Sh. Nabiev |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Diffraction
Materials science 010304 chemical physics Matrix isolation Binary number Crystal structure 010402 general chemistry 01 natural sciences Spectral line 0104 chemical sciences Electron diffraction 0103 physical sciences Molecule Physical chemistry Lewis acids and bases Physical and Theoretical Chemistry |
| Zdroj: | Russian Journal of Physical Chemistry B. 14:243-253 |
| ISSN: | 1990-7923 1990-7931 |
| DOI: | 10.1134/s1990793120020281 |
| Popis: | The most reliable data on the structure of individual gold(I, III, V–VII) fluorides in different physical states under matrix isolation and ultrahigh pressure conditions were presented and summarized. The vibrational spectra of binary gold fluorides in different oxidation states were analyzed. Special attention was paid to the spectra of the anomalously strong Lewis acid AuF5. The molecular structure of AuFk (k = 4–7) and AumFn (m = 2, 3; n = 6, 9) in the condensed state was conjectured based on the analysis of the spectroscopic, electron diffraction, and X-ray diffraction data and quantum-chemical calculations. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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