Synthesis, structure, and photoluminescent property of a trinuclear CdII complex based on semi-rigid bis(imidazole-4,5-dicarboxylate) ligand

Autor:	Xiang-Rong Hao, Zhong-Min Su, Gang Yuan, Ya-Ru Pan, Kui-Zhan Shao
Rok vydání:	2014
Předmět:	Photoluminescence Chemistry Ligand Stereochemistry Fluorescence Ion Inorganic Chemistry Metal Crystallography chemistry.chemical_compound visual_art Materials Chemistry visual_art.visual_art_medium Imidazole SBus Physical and Theoretical Chemistry Methylene
Zdroj:	Inorganic Chemistry Communications. 42:15-19
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2014.01.004
Popis:	A new 3D complex, {[Cd3(HL)2(H2L)(H2O)4]·2H2O}n (1) (H4L = 1,1′-(1,4-phenylenebis(methylene))bis(1H-imidazole-4,5-dicarboxylic acid), has been hydrothermally synthesized and characterized by elemental analyses, IR, TG, and X-ray single-crystal diffraction. Complex 1 is the first framework based on CdII ion and semi-rigid bis-IDC ligand. The (6,6)-net architecture of 1 is built from H2L2 − ligands linking 1D chain-like [Cd3(HL)2]n SBUs, which formed by HL3 − anions bridging two kinds of metal centers. In addition, complex 1 was demonstrated to display strong blue-violet fluorescence emission in the solid state at room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ed4e706721ceba461998d70693472e00 https://doi.org/10.1016/j.inoche.2014.01.004 Zobrazit plný text záznamu Full Text from ScienceDirect