Ionic iridium complex coordinated with tetrathiafulvalene-fused phenanthroline ligand: Synthesis, photophysical, electrochemical and electrochemiluminescence properties
| Autor: | Tian-Yi Li, Sheng-Yuan Deng, Jing-Lin Zuo, Chenxi Qian, Jie Qin, Huangxian Ju |
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| Rok vydání: | 2014 |
| Předmět: |
Ligand
Phenanthroline Organic Chemistry Cationic polymerization chemistry.chemical_element Ionic bonding Electrochemistry Photochemistry Biochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Electrochemiluminescence Iridium Physical and Theoretical Chemistry Tetrathiafulvalene |
| Zdroj: | Journal of Organometallic Chemistry. 750:7-12 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2013.10.041 |
| Popis: | A new cationic iridium(III) complex salt, [Ir(ppy)2(L)]PF6 (ppy = 2-phenylpyridine) (1), was synthesized by using tetrathiafulvalene fused 4′,5′-dimethyldithiotetrathiafulvenyl[4,5-f][1,10]phenanthroline (L) as NˆN ancillary ligand. The photophysical, electrochemical and electrochemiluminescence (ECL) behavior of the complex are investigated. Complex 1 is found to be emissive at room temperature with the λmax value at 607 nm. It is expected that this new luminescent complex 1 would be further explored for promising applications in functional emitting material. |
| Databáze: | OpenAIRE |
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