Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B–C bond cleavage
| Autor: | Alexander Okorn, Arumugam Jayaraman, Lukas Englert, Merle Arrowsmith, Theresa Swoboda, Jeanette Weigelt, Carina Brunecker, Merlin Hess, Anna Lamprecht, Carsten Lenczyk, Maximilian Rang, Holger Braunschweig |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Chemical Science. 13:7566-7574 |
| ISSN: | 2041-6539 2041-6520 |
| Popis: | In contrast to classical B–B bond-centred diborene hydrogenation, polycyclic aromatic hydrocarbon-substituted diborenes first undergo thermal intramolecular hydroarylation, followed by hydrogenation of the remaining B–B and endocyclic B–C bonds. |
| Databáze: | OpenAIRE |
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