Phenolate-bridged A2B-type subporphyrin dimer

Autor:	Shoma Hirokawa, Soji Shimizu, Nagao Kobayashi, Shigeki Mori
Rok vydání:	2021
Předmět:	chemistry.chemical_compound chemistry Stereochemistry Dimer Substituent General Chemistry Ether cleavage
Zdroj:	Journal of Porphyrins and Phthalocyanines. 25:975-980
ISSN:	1099-1409 1088-4246
Popis:	An ether cleavage reaction of A2B-type subporphyrin bearing an ortho-anisyl substituent afforded a phenolate-bridged dimer. A head-to-tail structure of the dimer was unambiguously elucidated by single crystal X-ray diffraction analysis. UV-vis absorption and magnetic circular dichroism spectra indicated a minor interaction between the subporphyrin chromophores. Density functional theory calculations provided a detailed insight into the electronic structures of the subporphyrin dimer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ed2db61f9a8c197468ed61af4ae3cb8e https://doi.org/10.1142/s1088424621500796 Zobrazit plný text záznamu