Metal Complexes with the N-Heterocyclic Ligand: Synthesis, Structures, and Thermal Decomposition

Autor:	Nikolay P. Simonenko, M. O. Grigor’eva, I. V. Skabitskii, O. G. Tikhonova, S. S. Shapovalov
Rok vydání:	2019
Předmět:	General Chemical Engineering Thermal decomposition chemistry.chemical_element General Chemistry Metal Thermogravimetry chemistry.chemical_compound Nickel Crystallography chemistry Ferrocene visual_art visual_art.visual_art_medium Moiety Cobalt Carbene
Zdroj:	Russian Journal of Coordination Chemistry. 45:706-711
ISSN:	1608-3318 1070-3284
DOI:	10.1134/s1070328419100063
Popis:	The heterometallic nickel and iron chalcogenide complexes, (η5-C5H5)Ni(MeIm)S(µ2-SnPr)Mn(CO)2(η5-C5H5) (I) and (η5-C5H5)Fe(MeIm)(CO)(µ2-SPh)Mn(CO)2(η5-C5H5) (II), and the cobalt nitrosyl complex (MeIm)Co(NO)2I (IIIa, IIIb) (CIF files CCDC nos. 1911962 (I), 1911963 (II), 1911964 (IIIa), and 1911965 (IIIb)) are synthesized and structurally characterized. According to the data of thermogravimetry and differential scanning calorimetry (TG–DSC), the organic moiety of the molecule of complex I is lost to form the NiMnS residue, whereas ferrocene is formed upon the thermal decomposition of complex II.
Databáze:	OpenAIRE
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