Conversion of Glucose to 5-hydroxymethylfurfural with Tetraethylammonium Bromide and Chromium (III) Chloride as Catalysts

Autor:	Yong Nie, Xue Jun Liu, Jian Bing Ji, Haiyan Zhang, Ning Ai
Rok vydání:	2013
Předmět:	chemistry.chemical_element Fructose General Medicine Chloride Catalysis Chromium(III) chloride Solvent chemistry.chemical_compound Chromium chemistry Yield (chemistry) medicine Tetraethylammonium bromide Nuclear chemistry medicine.drug
Zdroj:	Applied Mechanics and Materials. :157-160
ISSN:	1662-7482
DOI:	10.4028/www.scientific.net/amm.316-317.157
Popis:	Tetraethylammonium bromide (TEAB) and chromium (III) chloride (CrCl3) were used synergistically to catalyze the conversion of glucose to 5-hydroxymethylfurfural (HMF). The effects of solvent, catalyst loading, reaction temperature and reaction time on the HMF yields were investigated. The results indicated that using 70 mol% TEAB and 12 mol% CrCl3 in a 10 wt% fructose solution in N,N-dimethylacetamide (DMAC) gave the highest HMF yield of 72.7 % after 90 min at 120 °C
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eceffb62bfbe0cd47265a0d8df34f3e5 https://doi.org/10.4028/www.scientific.net/amm.316-317.157 Zobrazit plný text záznamu