Autor:	S. M. Esakov, A. Petrov, B. Ershov
Rok vydání:	1979
Předmět:	chemistry.chemical_compound Dipole chemistry Conductometry Physical chemistry Ionic bonding Methanol Rotation Spectroscopy Ion
Zdroj:	Magnetic Resonance and Related Phenomena ISBN: 9783642813467
DOI:	10.1007/978-3-642-81344-3_422
Popis:	Configuration stability and stereodynamics of different ionic particles in alcaline derivatives of 1,3-dicarbonyl compounds’ solutions were investigated by 1H and 13C spectroscopy and conductometry. In aprotic dipolar solvents and methanol free ions were proved to give the main contribution to the “trans” (E,Z and E,E) form. E,Z⇄E,E transition was shown to be a rotation in a “free” enolate-anion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ecee4b5154f1743aa0454c5001fb5afc https://doi.org/10.1007/978-3-642-81344-3_422 Zobrazit plný text záznamu