Chemical transformations on the [60] fullerene framework via aziridination processes
| Autor: | J. I. G. Cadogan, Philip K. G. Hodgson, David W. H. Rankin, Patrick R. R. Langridge-Smith, Ian Gosney, Malcolm R. Banks |
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| Rok vydání: | 1996 |
| Předmět: |
Fullerene derivatives
Fullerene Chemistry Mechanical Engineering Nitrene Metals and Alloys Condensed Matter Physics Photochemistry Chemical synthesis Electronic Optical and Magnetic Materials Adduct Mechanics of Materials Yield (chemistry) Materials Chemistry Organic chemistry Singlet state Isomerization |
| Zdroj: | Synthetic Metals. 77:77-80 |
| ISSN: | 0379-6779 |
| DOI: | 10.1016/0379-6779(96)80062-2 |
| Popis: | Isolation of closed 6,6-bridged aziridinofullerenes 2 by reaction of [60] fullerene with singlet oxycarbonylnitrenes is accompanied by small amounts of previously undetected closed 5,6-adducts 4 , thought to arise by trapping of triplet nitrenes. Isomerization of the 6,6-bridged adducts to the corresponding oxazolo[4′,5′:1,2] [60] fullerene derivatives 3 occurs upon heating with the exception of the tert-butoxycarbonyl adduct which eliminates isobutene and CO 2 to yield the parent aziridinofullerene C 60 NH 6 . |
| Databáze: | OpenAIRE |
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