14N and 39K Nuclear Quadrupole Coupüng in KNO3

Autor: S. N. Stuart, T. J. Bastow
Rok vydání: 1990
Předmět:
Zdroj: Zeitschrift für Naturforschung A. 45:459-463
ISSN: 1865-7109
0932-0784
DOI: 10.1515/zna-1990-3-442
Popis: The nuclear quadrupole interaction tensors of 14N and 39K in potassium nitrate at room temperature have been determined from nuclear magnetic resonance (NMR) rotation studies of single crystals at 9.4 T. Values for the coupling constants and asymmetry parameters at 296 K are: 14N: e2 qQ/h = 751 kHz, η = 0.022; 39K: e2 qQ/h = 1326kHz, η = 0.171. The temperature dependence, on approaching the order-disorder phase transition near 401 K, is linear.
Databáze: OpenAIRE