14N and 39K Nuclear Quadrupole Coupüng in KNO3
Autor: | S. N. Stuart, T. J. Bastow |
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Rok vydání: | 1990 |
Předmět: | |
Zdroj: | Zeitschrift für Naturforschung A. 45:459-463 |
ISSN: | 1865-7109 0932-0784 |
DOI: | 10.1515/zna-1990-3-442 |
Popis: | The nuclear quadrupole interaction tensors of 14N and 39K in potassium nitrate at room temperature have been determined from nuclear magnetic resonance (NMR) rotation studies of single crystals at 9.4 T. Values for the coupling constants and asymmetry parameters at 296 K are: 14N: e2 qQ/h = 751 kHz, η = 0.022; 39K: e2 qQ/h = 1326kHz, η = 0.171. The temperature dependence, on approaching the order-disorder phase transition near 401 K, is linear. |
Databáze: | OpenAIRE |
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