| Autor: |
M. D. Rudd, Sergey V. Lindeman, Steinar Husebye |
| Rok vydání: |
1997 |
| Předmět: |
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| Zdroj: |
Acta Crystallographica Section C Crystal Structure Communications. 53:809-811 |
| ISSN: |
0108-2701 |
| DOI: |
10.1107/s0108270197000309 |
| Popis: |
The crystal structure of N-methyl-1,3-benzothiazole-2(3H)-selone (mbts) has been studied in order to estimate the changes in the molecular geometry of the mbts ligand upon coordination. Hypervalent complexes of mbts with Te II and I I have been studied by us previously. A significant elongation of the Se=C bond [from 1.817 (7) in mbts to 1.85-1.88 A in the complexes] was found, but there were no significant changes in the other geometric parameters of the ligand. The only other bond-length decrease of note was for SeC-NMe [from 1.35 (1) in mbts to 1.32-1.34 A in the complexes]. Thus, only the amino group takes part in electron redistribution upon coordination. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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