Antituberculosis, Antifungal and Photoluminescence Studies on a Mn(II)–Neocuproine Complex

Autor:	Ali Nemati Kharat, Zahra Vosoughi Rahbari
Rok vydání:	2012
Předmět:	Neocuproine chemistry.chemical_compound Crystallography Denticity Photoluminescence chemistry Octahedron Ligand Stacking Molecule General Chemistry Methanol
Zdroj:	Journal of Chemical Research. 36:34-37
ISSN:	2047-6507 1747-5198
Popis:	The complex [Mn(Me2phen)(H2O)3(MeOH)][NO3]2, (Me2phen = 2,9-dimethyl-1,10-phenanthroline, neocuproine) has been prepared. Structural studies show that the [Mn (Me2phen) (H2O)3(MeOH)] cation is a six coordinate octahedral species with bidentate Me2phen and monodentate water and methanol ligands. The water molecules are hydrogen bonded to a Me2phen free ligand, which is co-crystallised in a position adjacent to the Mn complex. Face-to-face π···π stacking interactions between coordinated and free Me2phen ligand molecules generate an efficient parallel packing system in the complex, which also shows antituberculosis and antifungal activity. Photoluminescence properties are also reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ec82b4bc32cd6dc747cd33bb7b19dd09 https://doi.org/10.3184/174751912x13263085240144 Zobrazit plný text záznamu Plný text ve formátu PDF