Unprecedented anomalous stereochemistry of halogen additions to syn- and anti-9,9′-bibenzonorbornenylidenes

Autor:	Koichi Noda, Yoshiaki Sugihara, Juzo Nakayama
Rok vydání:	2000
Předmět:	Syn and anti addition Chemistry Stereochemistry Organic Chemistry Drug Discovery Halogen Biochemistry Inversion (discrete mathematics)
Zdroj:	Tetrahedron Letters. 41:8907-8911
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)01604-x
Popis:	Exclusive syn ( cis )-addition of Br 2 to syn -9,9′-bibenzonorbornenylidene ( 1 ) took place to give the corresponding vic -dibromide ( 3 ) quantitatively with retention of the configuration of 1 . Meanwhile, anti ( trans )-addition of Br 2 to anti -9,9′-bibenzonorbornenylidene ( 2 ) also occurred furnishing the same dibromide 3 quantitatively with inversion of the configuration of 2 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ec63a4691f6e39d4a83bb14378418ab0 https://doi.org/10.1016/s0040-4039(00)01604-x Zobrazit plný text záznamu Full Text from ScienceDirect