Zero kinetic energy proton and deuteron production from photoionization of H2 and D2

Autor:	J. N. Cutler, Z. X. He, James A. R. Samson, L. R. Hughey, S. H. Southworth
Rok vydání:	1995
Předmět:	Deuterium Proton Autoionization Chemistry Excited state Physics::Atomic and Molecular Clusters General Physics and Astronomy Zero-point energy Photoionization Physical and Theoretical Chemistry Atomic physics Kinetic energy Ion
Zdroj:	The Journal of Chemical Physics. 103:3912-3916
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.470692
Popis:	A zero ion kinetic energy spectrometer has been developed to study the production of near zero energy protons and deuterons from dissociative photoionization of H2 and D2. Both H+ and D+ spectra show four peaks on top of a continuum. The continuum was found to be in excellent agreement with the single center Coulomb calculation for the direct dissociation through the X 2Σ+g state of H+2. The observed structures were shown to originate from autoionization of the doubly excited Q1 1Σ+g(1), Q1 1Σ+u(1), Q1 1Σ+u(2), and Q2 1Σ+u(1) states, of which the Q1 1Σ+g(1) state is dipole forbidden.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ec411ad8616a9edb683352d1ce176303 https://doi.org/10.1063/1.470692 Zobrazit plný text záznamu