Importance of Relativistic Effects for Carbon as an NMR Reporter Nucleus in Carbide-Bridged [RuCPt] Complexes
| Autor: | Anders Reinholdt, Iben Glent-Madsen, Stephan P. A. Sauer, Jesper Bendix |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
010405 organic chemistry
Chemistry Ligand Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences Ruthenium Carbide Inorganic Chemistry Crystallography medicine.anatomical_structure medicine Physical and Theoretical Chemistry Platinum Relativistic quantum chemistry Nucleus Carbon |
| Zdroj: | Organometallics. 40:1443-1453 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/acs.organomet.1c00079 |
| Popis: | Carbide-bridged ruthenium platinum complexes of the general formula trans-(Cy3P)2Cl2Ru≡C–PtCl2-L show a remarkable ability to probe the ligand donor strength of the ligand L. An experimentally obse... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|