Properties of triphenylphosphite-modified rhodium carbonyl catalysts for the hydroformylation of 2-butenes

Autor:	N. V. Kolesnichenko, G. A. Korneeva, A. V. Shishin, O. L. Butkova, E. V. Slivinskii, E. E. Nifant'ev, S. M. Loktev, N. A. Markova, A. T. Teleshev
Rok vydání:	1990
Předmět:	Reaction conditions Hydrolysis Partial hydrolysis Chemistry Ligand Organic chemistry chemistry.chemical_element General Chemistry Medicinal chemistry Hydroformylation Catalysis Rhodium
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:2457-2461
ISSN:	1573-9171 0568-5230
Popis:	The factor responsible for the deactivation of a carbonyl triphenylphosphite rhodium hydroformylation catalyst appears to be the formation of a chelate-structure complex with diphenylphosphite, which is the product of partial hydrolysis of the organophosphorus ligand. The deactivating effect of diphenylphosphite can be suppressed upon interaction of the H(O)P(OPh)2 and P(OPh)3-modified complex with 2-butenes under hydroformylation reaction conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ec2ac3c9543c2ff62472b11b8599734c https://doi.org/10.1007/bf01184517 Zobrazit plný text záznamu Full text from SpringerLink