4,4′-Coupled bis(isoquinolines)

Autor: Bardia Guilani, Harry W. Gibson, Melvin L. Rasco, Christine F. K. Hermann
Rok vydání: 1990
Předmět:
Zdroj: Journal of Heterocyclic Chemistry. 27:1007-1009
ISSN: 1943-5193
0022-152X
DOI: 10.1002/jhet.5570270436
Popis: Reaction of the eneamine 1 formed in situ from isoquinoline and sodium triethylborohydride with aromatic dialdehydes 3 produces 4,4′-coupled bis(isoquinolines) 4 in good yields. These compounds are readily oxidized with manganese dioxide to the corresponding diketones 5.
Databáze: OpenAIRE