Synthesis and characterization of Hg(II) and Zn(II) complexes based on 3-[(4-chlorophenylamido)]propenoic acid

Autor:	S. Shahzadi, M. Z. Ali, Syed Mansoor Ali
Rok vydání:	2011
Předmět:	Ethanol Ligand Materials Science (miscellaneous) Inorganic chemistry Maleic anhydride Conductance Medicinal chemistry Inorganic Chemistry Metal chemistry.chemical_compound Acetic acid chemistry visual_art visual_art.visual_art_medium Carboxylate Physical and Theoretical Chemistry Spectroscopy
Zdroj:	Russian Journal of Inorganic Chemistry. 56:1752-1756
ISSN:	1531-8613 0036-0236
DOI:	10.1134/s0036023611110027
Popis:	3-[(4-Chlorophenylamido)]propenoic acid has been synthesized by reaction of maleic anhydride and 4-chloroaniline in 1:1 molar ratio in glacial acetic acid and its metal complexes have been synthesized by the reaction of 3-[(4-chlorophenylamido)]propenoic acid with HgCl2 and [Zn(CH3COO)2] · 2H2O in 2: 1 molar ratio, respectively. All the synthesized compounds have been characterized by the elemental analysis, IR, UV/Vis and NMR (1H, 13C) spectroscopy. Conductance for the reported compounds has been recorded in ethanol and suggests the non-electro lytic nature of complexes. IR data of metal complexes shows that the ligand is bound to the metal via both carboxylate oxygen atoms and complexes exhibits 4-coordinated geometry in solid state. NMR (1H, 13C) study confirms the structure of the 3-[(4-chlorophenylamido)]propenoic acid and the reported complexes.
Databáze:	OpenAIRE
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