| Autor: |
Juba Ghouilem, Sokna Bazzi, Nicolas Grimblat, Pascal Retailleau, Vincent Gandon, Samir MESSAOUDI |
| Rok vydání: |
2022 |
| DOI: |
10.26434/chemrxiv-2022-fwgr0 |
| Popis: |
The first example of Pd(II)-catalyzed anomeric arylation of 3-aminosugars is reported by using an L,X-type transient directing groups (TDG) approach combined with an external 2-pyridone ligand. The released free amine was in situ transformed into an azide function, which was then exploited in a CuAAC to increase the molecular complexity and prepare a variety of complex substituted C3-triazolo C-glycosides in good yields. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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