Catalyst concentration effect on the hydroesterification and hydroformylation-acetalization of 1-hexene by a rh complex

Autor:	Juan Carlos Alvarez, Fernando Hung-Low, Alvaro J. Pardey, Gabriela C. Uzcátegui, Clementina Longo, Marisol C. Ortega
Rok vydání:	2006
Předmět:	Concentration effect chemistry.chemical_element Catalysis Water-gas shift reaction Heptanal Rhodium 1-Hexene chemistry.chemical_compound chemistry Organic chemistry Methanol Physical and Theoretical Chemistry Hydroformylation
Zdroj:	Reaction Kinetics and Catalysis Letters. 88:143-148
ISSN:	1588-2837 0133-1736
Popis:	The complex, [Rh(COD)(4-picoline)2](PF6) (COD = 1,5-cyclooctadiene), immobilized on poly(4-vinylpyridine) in contact with methanol catalyzes the hydroesterification and hydroformylation-acetalization of 1-hexene to methylheptanoate, heptanal and 1,1-dimethoxyheptane, respectively. The by-product, 1,1-dimethoxyheptane comes from the nucleophilic addition of methanol over the heptanal formed. Also, H2 and CO2 from the water gas shift reaction (WGSR) are observed. The catalytic activity for the hydroformylation and the WGSR proved to be non-linear in the rhodium total concentration range 0.9-5.0 wt.%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ec0bb7268e3840a8c09a2ee9c1b4a6d9 https://doi.org/10.1007/s11144-006-0127-y Zobrazit plný text záznamu Full text from SpringerLink