An enantiomeric pair of sodium(I) organic/inorganic frameworks having novel two-dimensional inorganic comb-like separating layers

Autor:	Zhaolian Chu, Li Wang, Shaohua Gou, Wei Huang
Rok vydání:	2009
Předmět:	Schiff base Sodium Condensation chemistry.chemical_element Sodium salt Inorganic Chemistry chemistry.chemical_compound chemistry Organic inorganic Polymer chemistry Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Enantiomer Chirality (chemistry)
Zdroj:	Inorganic Chemistry Communications. 12:4-7
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2008.10.014
Popis:	An enantiomeric pair of sodium(I) directed organic/inorganic frameworks have been obtained via the Schiff base condensation between terephthaldicarboxaldehyde and sodium salts of D- or L-phenylalanine wherein two novel two-dimensional (2D) inorganic sodium(I) separating layers composed of fully fused twelve-membered [Na6(H2O)12] comb-like rings are constituted. To the best of our knowledge, they are the first structural examples of terephthaldicarboxaldehyde-based chiral Schiff base compounds and 2D [Nax(H2O)y]n robust inorganic frameworks.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ec0935d69a89dcb65f6a9d9fc17688f8 https://doi.org/10.1016/j.inoche.2008.10.014 Zobrazit plný text záznamu Full Text from ScienceDirect