ortho-Cycloboronation of a Thiobenzoate Cluster: [(PPh3)(PhC\bridge{OS)$_{2}$NiB}{12.5mm}10H10].0.5C6H14
Autor: | Pei-Ju Zheng, Chunhua Hu, H.-J. Yao, Wei Li, J.-M. Dou, R.-S. Jin |
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Rok vydání: | 1997 |
Předmět: | |
Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 53:695-697 |
ISSN: | 0108-2701 |
Popis: | The title compound, 2,7:3,7-di(μ-thiobenzoato-S:O)-7-(triphenylphosphine-P)-8,9:10,11-di-μH– 7-nickela-nido-undecaborane–hexane (1/0.5), C32H35B10NiO2PS2.0.5C6H14, has been synthesized and characterized by X-ray diffraction analysis. The Ni atom is bound to one PPh3 ligand, two S atoms and four B atoms of the {NiB10} cage. The ortho-cycloboronation of thiobenzoates produces two five-membered Ni—S—C—O—B rings. |
Databáze: | OpenAIRE |
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