Donor-acceptor properties of ligands in transition metal coordination compounds by X-ray photoelectron spectroscopy
| Autor: | M.A. Porai-Koshits, V.I. Nefedov |
|---|---|
| Rok vydání: | 1972 |
| Předmět: |
Ligand field theory
chemistry.chemical_classification Metal K-edge Ligand Chemistry Mechanical Engineering Binding energy Condensed Matter Physics Photochemistry Metal L-edge Coordination complex Crystallography Transition metal Mechanics of Materials Metal–ligand multiple bond General Materials Science |
| Zdroj: | Materials Research Bulletin. 7:1543-1552 |
| ISSN: | 0025-5408 |
| DOI: | 10.1016/0025-5408(72)90192-4 |
| Popis: | The data obtained by the ESCA-investigation of ∼250 coordination compounds of Pd, Pt, Rh, Ir, Re allowed us to establish the dependence of binding energy of a metal upon its oxidation number and the composition of a complex, to compose a series of ligands by their ability to draw electron density off a metal, to consider donor-acceptor properties of neutral ligands, to find partial ligand contributions to a binding energy shift of a metal and to analyse some aspects of ligand interrelation, the trans-influence of multiple bonded ligands in particular. |
| Databáze: | OpenAIRE |
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