The structure of thiophene sesquioxide:Syn, endo-3a,4,7,7a-tetrahydro-4,7-epithiobenzo[b] thiophene 1,1,8-trioxide

Autor:	Ronald E. Merrill, Gary Sherwood
Rok vydání:	1977
Předmět:	chemistry.chemical_compound Sesquioxide Radical ion Chemistry Organic Chemistry Mass spectrum Thiophene Carbon-13 NMR Photochemistry Benzene Medicinal chemistry Trioxide
Zdroj:	Journal of Heterocyclic Chemistry. 14:1251-1253
ISSN:	1943-5193 0022-152X
DOI:	10.1002/jhet.5570140723
Popis:	Thiophene sesquioxide is shown to be syn, endo-3a,4,7,7a-tetrahydro-4,7-epithiobenzo[b]-thiophene 1,1,8-trioxide (I) by 1 H and 13 C nmr evidence. Assignment of the 13 C spectrum was facilitated by a cross-ring long-range 13 C-1 H coupling. The mass spectrum of I is dominated by an unusual break-down to give benzene radical cation.
Databáze:	OpenAIRE
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