ChemInform Abstract: Synthesis of Vicinal 2,3-Dialkyl-6-hydroxybenzophenones by Titanium Tetrachloride Catalyzed Fries Rearrangement of 3,4-Dialkylphenyl Benzoates

Autor:	Robert Martin, Pierre Demerseman
Rok vydání:	2010
Předmět:	Fries rearrangement Halogenation chemistry.chemical_element General Medicine Medicinal chemistry Benzoates Catalysis chemistry.chemical_compound chemistry Yield (chemistry) Titanium tetrachloride Organic chemistry Vicinal Titanium
Zdroj:	ChemInform. 23
ISSN:	0931-7597
Popis:	The titanium(IV) chloride-mediated Fries rearrangement of 3,4-dialkylphenyl benzoates 1 yields mainly 4,5-dialkyl-2-hydroxy-benzophenones 2 in high yield. We describe here a new access to the unknown vicinal 2,3-dialkyl-6-hydroxybenzophenones 3, which is based on the protection of the most reactive position of 1 by bromination
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ebd61a3f8ecdc0278b21f5284cdcdc49 https://doi.org/10.1002/chin.199250141 Zobrazit plný text záznamu Plný text