ChemInform Abstract: SOLVOLYSE DES TETRATHIOCYANATO-DIANILINO-CHROMAT(III)-IONS IN ACETON-WASSER-MISCHUNGEN

Autor:	I. Ganescu, Valeriu Voiculescu, Csaba Várhelyi
Rok vydání:	1975
Předmět:	chemistry.chemical_compound Order of reaction Aniline chemistry Polymer chemistry Acetone Molecule Amine gas treating General Medicine Perchloric acid Solvolysis Ion
Zdroj:	Chemischer Informationsdienst. 6
ISSN:	0009-2975
DOI:	10.1002/chin.197537350
Popis:	The solvolysis of the [Cr(NCS)4(aniline)2]− complex ion has been studied in various acetone-water mixtures in the presence of perchloric acid (10−3–10−1 mole/l). In acid solutions the first two NCS− ions are exchanged, presumably, for water molecules and in parallel an aniline molecule for acetone, the latter in a second order reaction, accelerated by hydrogen ions. The exchange of the amine is followed by the substitution of the first two NCS− ions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ebbfa006795e68d85add5a07c81f481e https://doi.org/10.1002/chin.197537350 Zobrazit plný text záznamu Plný text