Facile synthesis of a sandwiched Ti3C2Tx MXene/nZVI/fungal hypha nanofiber hybrid membrane for enhanced removal of Be(II) from Be(NH) complexing solutions

Autor: Zhihui Yang, Luo Siyuan, Congjian Tang, Qingwei Wang, Shunhong Huang, Runhua Chen, Yangyang Wang, Ping Wang, Yuying Cheng, Xiang Siyuan, Changqing Su
Rok vydání: 2021
Předmět:
Zdroj: Chemical Engineering Journal. 421:129682
ISSN: 1385-8947
DOI: 10.1016/j.cej.2021.129682
Popis: Two-dimensional metal carbides or nitrides (MXenes) demonstrate various excellent properties; however, their poor permeability precludes their application in water treatment. In this study, Ti3C2Tx MXene/nZVI/fungal hyphae nanofiber hybrid membranes (MXene/nZVI@FH) were prepared by chemical-intensive precipitation method for the robust capture of Be(II) from a beryllium-ammonia complexing solution. Interestingly, the MXene/nZVI@FH membrane showed favorable water permeability (6.10 × 10−15 m2), which was approximately 301 times higher than that of a pure Ti3C2Tx membrane, and 99.8% Be(II) was captured from the Be(NH2)2 complexing solution with an extremely low concentration (19.85 ppm). Specifically, the maximum Be(II) adsorption capacity of MXene/nZVI@FH was calculated to be 95.20 mg/g from the Be(NH2)2 complexing solution at pH 5.0 and 35 °C. Various characterization results (e.g., SEM, FTIR, XRD, VSM and XPS) suggested that Be(II) prefers to coordinate with surface oxygen groups bonded to the MXene nanosheets by forming BeO and BeO22− bidentate inner-sphere complexes. Furthermore, due to its reticular sandwiched structure, MXene/nZVI@FH could be easily activated and reused by leaching with 0.1 M HCl solution. Thus, it is a promising hybrid membrane for the removal and recovery of Be(II) from a Be(NH2)2 complexing solution.
Databáze: OpenAIRE
Externí odkaz: