| Autor: |
Phuong T. Dang, Canh D. Dao, Huyen T. Pham, Hy G. Le, Tien Q. Phi, Tuan A. Vu, Thao T. H. Phan |
| Rok vydání: |
2011 |
| Předmět: |
|
| Zdroj: |
SPIE Proceedings. |
| ISSN: |
0277-786X |
| Popis: |
Hybrid nanoporous MCF, SBA-15 and MCM-41 materials were synthesized via hydrothermal treatment and functionalized with 3-aminopropyltriethoxysilane (APTES) via post-synthesis grafting and sequently activated by glutardialdehyde and then were used to immobilize D-amino acid oxidase (DAAO). The amino-functionalized materials were characterized by various techniques: XRD, IR and N2 adsorption-desorption (BET). From characterization results, it indicated that these materials still maintained their structure after functionalization. The data IR and TGA-DTA analysis demonstrated the incorpotation of amine functional groups on the surface of APTES-functionalized samples. The DAAO immobilized on functionalized materials exhibited higher catalytic activity and stability for conversion of cephalosporin C (CPC) compare to those of non-functionalized one. Further more, the catalytic activity as well as stability of enzyme decreased in order MCF > SBA-15 > MCM-41 with the decrease of their pore size. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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