Comparative hydrogenation of quinones of complex steric structure

Autor: L. V. Antik, E. I. Klabunovskii, A. A. Balandin
Rok vydání: 1964
Předmět:
Zdroj: Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 13:1694-1700
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00849430
Popis: 1. A comparative hydrogenation of quinones of the bicyclic series over a Raney nickel catalyst was conducted at 45° and atmospheric pressure in dioxane medium. 2. The sterically complex structure of the bicyclic quinones prevents the occurrence of the insertion of hydrogen into the side ring and has little effect on the rate of hydrogenation of the quinoid portion of the molecule.
Databáze: OpenAIRE