Ferroelectric properties of vinylidene fluoride‐trifluoroethylene copolymers

Autor:	Toyoki Kitayama, Yamada Takeshi
Rok vydání:	1981
Předmět:	chemistry.chemical_classification Materials science Transition temperature Analytical chemistry General Physics and Astronomy Dielectric Polymer Ferroelectricity Hysteresis Nuclear magnetic resonance chemistry X-ray crystallography Copolymer Curie temperature
Zdroj:	Journal of Applied Physics. 52:6859-6863
ISSN:	1089-7550 0021-8979
DOI:	10.1063/1.328679
Popis:	The ferroelectric properties of vinylidene fluoride‐trifluoroethylene copolymers were studied. According to the x‐ray diffraction patterns, the crystalline form of the copolymers with VDF molar content less than 80% was different from that of the copolymer with 82 mole % VDF. The Curie temperature was observed for the copolymers with the molar composition ranging from 37 to 80% in VDF by measuring the dielectric constants and endothermic peaks. The copolymers with low Curie temperature had the crystalline with wide interplanar spacing and small saturation polarization. The copolymer with 55 mole % of VDF showed a typical ferroelectric D‐E hysteresis loop at 25 °C and showed a double hysteresis loop at just below the transition temperature.
Databáze:	OpenAIRE
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