Solution and solid state conformation of Fischer carbene complexes vis-à-vis conformation of aryl carboxamides: complexation of the aromatic ring by tricarbonylchromium makes a difference

Autor:	Vedavati G. Puranik, Debasis Hazra, Amitabha Sarkar, Mohan M. Bhadbhade, K. N. Jayaprakash, Karl S. Hagen, Uttamkumar Samanta
Rok vydání:	2001
Předmět:	Chemistry Stereochemistry Aryl Transition metal carbene complex Organic Chemistry Solid-state Aromaticity Ring (chemistry) Biochemistry Inorganic Chemistry Proton nmr spectroscopy Crystallography chemistry.chemical_compound Materials Chemistry Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. :709-722
ISSN:	0022-328X
Popis:	Crystallography and proton NMR spectroscopy were used to compare the conformations of aryl amino Fischer carbene complexes with structurally analogous aryl carboxamides. The similarity disappears when the aromatic rings were complexed with tricarbonylchromium groups. Details of synthesis, spectral and analytical data for all new compounds are provided.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eb9260f132649795170c7f711c5a20cb https://doi.org/10.1016/s0022-328x(00)00728-2 Zobrazit plný text záznamu Full Text from ScienceDirect