Catalytic processing of atmospheric residue of petroleum over AlSBA-15 nanomaterials with different acidity
| Autor: | Regina C. O. B. Delgado, Cleyton K. D. Alberto, Kesia K. V. Castro, Antonio S. Araujo, Gabriel F. S. Barbosa, Ana C. F. Coriolano |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
General Chemical Engineering
Energy Engineering and Power Technology chemistry.chemical_element General Chemistry Activation energy 010402 general chemistry Geotechnical Engineering and Engineering Geology 01 natural sciences Nitrogen 010406 physical chemistry 0104 chemical sciences law.invention Nanomaterials Catalysis Diesel fuel Fuel Technology chemistry Chemical engineering Magazine law Gasoline Pyrolysis |
| Zdroj: | Petroleum Science and Technology. 34:627-632 |
| ISSN: | 1532-2459 1091-6466 |
| Popis: | The AlSBA-15 nanomaterials with different Si/Al ratios were investigated as a promising material for processing of atmospheric residue of petroleum (ATR). The processing was performed in a thermobalance using nitrogen as a carrier gas at different heating hates. The catalytic pyrolysis was performed with ATR sample containing 20% mass of AlSBA-15. Based on TG data by applying Ozawa-Flynn-Wall kinetic model, the activation energy for the pyrolysis of ATR was higher than for the ATR/AlSBA-15, throughout all range of decomposition, indicating that the nanostructured material is a promising material for processing petroleum residues in order to obtain liquid products in the gasoline and diesel range. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|