Synthesis and applications to asymmetric catalysis of a series of mono- and bis(diazaphospholidine) ligands

Autor:	Colin David Eldred, Donald Smyth, Martin Wills, Nathaniel W. Alcock, Heather Tye
Rok vydání:	2001
Předmět:	Substitution reaction Allylic rearrangement chemistry.chemical_compound Chemistry Diamine Condensation Enantioselective synthesis Organic chemistry Medicinal chemistry
Zdroj:	Journal of the Chemical Society, Perkin Transactions 1. :2840-2849
ISSN:	1364-5463 1472-7781
DOI:	10.1039/b106399p
Popis:	The synthesis of a series of closely related mono- and bis(diazaphospholidine) ligands has been achieved using the condensation of a diamine with a bis(dimethylamino)arylphosphine. The resulting ligands have given excellent results in palladium-catalysed allylic substitution reactions to form C–C bonds (up to 89% ee) and C–N bonds (up to 78% ee).
Databáze:	OpenAIRE
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