A Convenient One-Pot Synthesis of Di-t-butylphosphinic Chloride

Autor:	D. Michael Heinekey, Karen I. Goldberg, Werner Kaminsky, Daniel F. Brayton
Rok vydání:	2008
Předmět:	Chemistry Organic Chemistry One-pot synthesis Crystal structure Biochemistry Chemical synthesis Chloride Medicinal chemistry Inorganic Chemistry Group (periodic table) medicine Organic chemistry medicine.drug Monoclinic crystal system
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 183:2534-2540
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426500801967781
Popis:	A convenient one-pot synthesis of (t-Bu)2P(O)Cl (1) from m-chloroperbenzoic acid and (t-Bu)2PCl is described. The byproduct m-chlorobenzoic acid is neutralized by addition of Et3N. Complex 1 crystallizes in the monoclinic space group P21/c (No. 14), with a = 5.9637(2) A, b = 11.4734(4) A, c = 16.2400(5) A and β = 107.7160(14).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eb73ff3301c8464583d25baccb473a3b https://doi.org/10.1080/10426500801967781 Zobrazit plný text záznamu