Electrochemical and spectroscopic studies on RuCl2(PPh3)2(N)2 and RuCl2(PPh3)2(N–N) complexes (N=pyridine derivatives and N–N=phenanthroline or bipyridine derivatives). X-ray structure of RuCl2(PPh3)2(phen)

Autor:	Claudio Luis Donnici, Salete L Queiroz, Peter Conrad Healy, Alzir A. Batista, Ícaro de Sousa Moreira, Marcelo O. Santiago, Susan J. Berners-Price
Rok vydání:	2001
Předmět:	Stereochemistry Phenanthroline Electrochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Bipyridine chemistry Pyridine Materials Chemistry Isonicotinamide Physical and Theoretical Chemistry Cyclic voltammetry Triphenylphosphine Single crystal
Zdroj:	Polyhedron. 20:2123-2128
ISSN:	0277-5387
Popis:	A series of RuCl2(PPh3)2(N)2 and RuCl2(PPh3)2(N–N) complexes were synthesized from RuCl2(PPh3)3, (N)2=pyridine (py), 4-(N,N-dimethylamino)pyridine (4-dmNpy), 4-tert-butylpyridine (4-tBu-py), 4-methylpyridine (4-Mepy), 4-vinylpyridine (4-Vpy), 4-phenylpyridine (4-Phpy), isonicotinamide (4-CONH2py), 4-cyanopyridine (4-CNpy) N–N=1,10-phenanthroline (phen), 2,2′-bipyridine (bipy), 2,2′-bipyridine-4,4′-dimethoxy (MeO-bipy), 2,2′-bipyridine-4,4′-dimethyl (Me-bipy), 2,2′-bipyridine-4,4′-dithiomethyl (MeS-bipy), 2,2′-bipyridine-4,4′-dichloro (Cl-bipy) and 2,2′-bipyridine-4,4′-dinitro (NO2-bipy). The complexes were characterized by elemental analysis, cyclic voltammetry and UV–Vis, NMR and IR spectroscopies. The structure of the RuCl2(PPh3)2(phen) was established by single crystal X-ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eb6424b74f8ccfe7edbf71f7e3484bd6 https://doi.org/10.1016/s0277-5387(01)00744-6 Zobrazit plný text záznamu Full Text from ScienceDirect