Amperometric Titration of Plutonium(VI) with Iron(II)

Autor:	R. J. Meyer, C. A. Seils, R. P. Larsen
Rok vydání:	1963
Předmět:	chemistry.chemical_compound chemistry Oxide chemistry.chemical_element Titration Sulfuric acid Electrochemistry Platinum Quantitative analysis (chemistry) Amperometric titration Analytical Chemistry Nuclear chemistry Plutonium
Zdroj:	Analytical Chemistry. 35:1673-1675
ISSN:	1520-6882 0003-2700
DOI:	10.1021/ac60204a040
Popis:	plutonium(VI) with iron(II) in which the end point is detected amperometrically with a rotnting platinum electrode. The plutonium is oxidized to the sexivalent state in a sulfuric acid medium with argentic oxide, the excess oxidant destroyed by heating, and the plutonium titrated by the addition of standard iron(II) suifate from special weight burets. For 15-mg samples, precisions of plus or minus 0.06% relative standard deviation are obtainable with no significant bias. For 0.2-mg samples, the relative standard deviation is 0.4% with a 0.6% negative bias. (auth)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eb53620b408a1c4ccb05f19b4a8f3d81 https://doi.org/10.1021/ac60204a040 Zobrazit plný text záznamu