[(2RS,5SR,8SR,12SR,15SR)-2,5,8,12,15-Pentaazahexadecane-κ5N2,5,8,12,15]copper(II) diperchlorate

Autor:	Yuh-Liang Liu, T. H. Tahirov, Chung-Sun Chung, Tian-Huey Lu
Rok vydání:	1994
Předmět:	Steric effects Stereochemistry Ligand chemistry.chemical_element General Medicine Crystal structure Ring (chemistry) Copper General Biochemistry Genetics and Molecular Biology Perchlorate chemistry.chemical_compound Crystallography chemistry Atom Molecule
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 50:514-516
ISSN:	0108-2701
DOI:	10.1107/s0108270193009783
Popis:	The Cu II atom in the title complex, [Cu(C 11 H 29 N 5 )](ClO 4 ) 2 , is five-coordinate and is in a distorted trigonal-bipyramidal conformation. The longer Cu(equatorial)-N bond distances compared to the Cu(axial)-N distances indicate the steric influence of the two N-methyl groups. The ligand is in its stable conformation with the three five-membered chelate rings in stable skew forms and the six-membered ring in a stable chair form
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eb316fa0993a40138797bdcea0b40128 https://doi.org/10.1107/s0108270193009783 Zobrazit plný text záznamu Plný text